diff --git a/tsc/internal/checker/checker.go b/tsc/internal/checker/checker.go
index d392785d4181f..c75355f13e696 100644
--- a/tsc/internal/checker/checker.go
+++ b/tsc/internal/checker/checker.go
@@ -24634,10 +24634,18 @@ func (c *Checker) evaluateEntity(expr *ast.Node, location *ast.Node) evaluator.R
 				name := expr.AsElementAccessExpression().ArgumentExpression.Text()
 				member := rootSymbol.Exports()[name]
 				if member != nil {
-					if location != nil {
-						return c.evaluateEnumMember(expr, member, location)
+					// Follow aliases like resolveEntityName (property-access path), e.g. export import C = F.A.
+					for member.Flags()&ast.SymbolFlagsValue == 0 && member.Flags()&ast.SymbolFlagsAlias != 0 {
+						member = c.resolveAlias(member)
+					}
+					// Merged namespace+enum symbols can export non-enum members (e.g. a class).
+					// Only treat EnumMember exports as constant enum values — mirror the identifier path.
+					if member.Flags()&ast.SymbolFlagsEnumMember != 0 {
+						if location != nil {
+							return c.evaluateEnumMember(expr, member, location)
+						}
+						return c.getEnumMemberValue(member.ValueDeclaration())
 					}
-					return c.getEnumMemberValue(member.ValueDeclaration())
 				}
 			}
 		}
diff --git a/tsc/testdata/baselines/reference/compiler/enumInitializerNamespaceExportElementAccess.errors.txt b/tsc/testdata/baselines/reference/compiler/enumInitializerNamespaceExportElementAccess.errors.txt
new file mode 100644
index 0000000000000..7818ffce72b99
--- /dev/null
+++ b/tsc/testdata/baselines/reference/compiler/enumInitializerNamespaceExportElementAccess.errors.txt
@@ -0,0 +1,28 @@
+enumInitializerNamespaceExportElementAccess.ts(8,9): error TS18033: Type 'typeof C' is not assignable to type 'number' as required for computed enum member values.
+
+
+==== enumInitializerNamespaceExportElementAccess.ts (1 errors) ====
+    // Namespace export merged with enum must not be treated as an enum member via E["C"].
+    // Previously panicked: Unhandled case in Node.MemberList: KindModuleBlock
+    
+    namespace E {
+        export class C {}
+    }
+    enum E {
+        D = E["C"],
+            ~~~~~~
+!!! error TS18033: Type 'typeof C' is not assignable to type 'number' as required for computed enum member values.
+    }
+    
+    // Alias exports that resolve to enum members must still constant-evaluate (like E.C).
+    enum F {
+        A = 1,
+    }
+    namespace E2 {
+        export import C = F.A;
+    }
+    enum E2 {
+        D = E2["C"],
+        Next,
+    }
+    
\ No newline at end of file
diff --git a/tsc/testdata/baselines/reference/compiler/enumInitializerNamespaceExportElementAccess.js b/tsc/testdata/baselines/reference/compiler/enumInitializerNamespaceExportElementAccess.js
new file mode 100644
index 0000000000000..e5312dbec4852
--- /dev/null
+++ b/tsc/testdata/baselines/reference/compiler/enumInitializerNamespaceExportElementAccess.js
@@ -0,0 +1,52 @@
+//// [tests/cases/compiler/enumInitializerNamespaceExportElementAccess.ts] ////
+
+//// [enumInitializerNamespaceExportElementAccess.ts]
+// Namespace export merged with enum must not be treated as an enum member via E["C"].
+// Previously panicked: Unhandled case in Node.MemberList: KindModuleBlock
+
+namespace E {
+    export class C {}
+}
+enum E {
+    D = E["C"],
+}
+
+// Alias exports that resolve to enum members must still constant-evaluate (like E.C).
+enum F {
+    A = 1,
+}
+namespace E2 {
+    export import C = F.A;
+}
+enum E2 {
+    D = E2["C"],
+    Next,
+}
+
+
+//// [enumInitializerNamespaceExportElementAccess.js]
+"use strict";
+// Namespace export merged with enum must not be treated as an enum member via E["C"].
+// Previously panicked: Unhandled case in Node.MemberList: KindModuleBlock
+var E;
+(function (E) {
+    class C {
+    }
+    E.C = C;
+})(E || (E = {}));
+(function (E) {
+    E[E["D"] = E["C"]] = "D";
+})(E || (E = {}));
+// Alias exports that resolve to enum members must still constant-evaluate (like E.C).
+var F;
+(function (F) {
+    F[F["A"] = 1] = "A";
+})(F || (F = {}));
+var E2;
+(function (E2) {
+    E2.C = F.A;
+})(E2 || (E2 = {}));
+(function (E2) {
+    E2[E2["D"] = 1] = "D";
+    E2[E2["Next"] = 2] = "Next";
+})(E2 || (E2 = {}));
diff --git a/tsc/testdata/baselines/reference/compiler/enumInitializerNamespaceExportElementAccess.symbols b/tsc/testdata/baselines/reference/compiler/enumInitializerNamespaceExportElementAccess.symbols
new file mode 100644
index 0000000000000..f5e6db5dfc5fe
--- /dev/null
+++ b/tsc/testdata/baselines/reference/compiler/enumInitializerNamespaceExportElementAccess.symbols
@@ -0,0 +1,48 @@
+//// [tests/cases/compiler/enumInitializerNamespaceExportElementAccess.ts] ////
+
+=== enumInitializerNamespaceExportElementAccess.ts ===
+// Namespace export merged with enum must not be treated as an enum member via E["C"].
+// Previously panicked: Unhandled case in Node.MemberList: KindModuleBlock
+
+namespace E {
+>E : Symbol(E, Decl(enumInitializerNamespaceExportElementAccess.ts, 0, 0), Decl(enumInitializerNamespaceExportElementAccess.ts, 5, 1))
+
+    export class C {}
+>C : Symbol(C, Decl(enumInitializerNamespaceExportElementAccess.ts, 3, 13))
+}
+enum E {
+>E : Symbol(E, Decl(enumInitializerNamespaceExportElementAccess.ts, 0, 0), Decl(enumInitializerNamespaceExportElementAccess.ts, 5, 1))
+
+    D = E["C"],
+>D : Symbol(E.D, Decl(enumInitializerNamespaceExportElementAccess.ts, 6, 8))
+>E : Symbol(E, Decl(enumInitializerNamespaceExportElementAccess.ts, 0, 0), Decl(enumInitializerNamespaceExportElementAccess.ts, 5, 1))
+>"C" : Symbol(E.C, Decl(enumInitializerNamespaceExportElementAccess.ts, 3, 13))
+}
+
+// Alias exports that resolve to enum members must still constant-evaluate (like E.C).
+enum F {
+>F : Symbol(F, Decl(enumInitializerNamespaceExportElementAccess.ts, 8, 1))
+
+    A = 1,
+>A : Symbol(F.A, Decl(enumInitializerNamespaceExportElementAccess.ts, 11, 8))
+}
+namespace E2 {
+>E2 : Symbol(E2, Decl(enumInitializerNamespaceExportElementAccess.ts, 13, 1), Decl(enumInitializerNamespaceExportElementAccess.ts, 16, 1))
+
+    export import C = F.A;
+>C : Symbol(C, Decl(enumInitializerNamespaceExportElementAccess.ts, 14, 14))
+>F : Symbol(F, Decl(enumInitializerNamespaceExportElementAccess.ts, 8, 1))
+>A : Symbol(C, Decl(enumInitializerNamespaceExportElementAccess.ts, 11, 8))
+}
+enum E2 {
+>E2 : Symbol(E2, Decl(enumInitializerNamespaceExportElementAccess.ts, 13, 1), Decl(enumInitializerNamespaceExportElementAccess.ts, 16, 1))
+
+    D = E2["C"],
+>D : Symbol(E2.D, Decl(enumInitializerNamespaceExportElementAccess.ts, 17, 9))
+>E2 : Symbol(E2, Decl(enumInitializerNamespaceExportElementAccess.ts, 13, 1), Decl(enumInitializerNamespaceExportElementAccess.ts, 16, 1))
+>"C" : Symbol(E2.C, Decl(enumInitializerNamespaceExportElementAccess.ts, 14, 14))
+
+    Next,
+>Next : Symbol(E2.Next, Decl(enumInitializerNamespaceExportElementAccess.ts, 18, 16))
+}
+
diff --git a/tsc/testdata/baselines/reference/compiler/enumInitializerNamespaceExportElementAccess.types b/tsc/testdata/baselines/reference/compiler/enumInitializerNamespaceExportElementAccess.types
new file mode 100644
index 0000000000000..ade9d221407d6
--- /dev/null
+++ b/tsc/testdata/baselines/reference/compiler/enumInitializerNamespaceExportElementAccess.types
@@ -0,0 +1,51 @@
+//// [tests/cases/compiler/enumInitializerNamespaceExportElementAccess.ts] ////
+
+=== enumInitializerNamespaceExportElementAccess.ts ===
+// Namespace export merged with enum must not be treated as an enum member via E["C"].
+// Previously panicked: Unhandled case in Node.MemberList: KindModuleBlock
+
+namespace E {
+>E : typeof E
+
+    export class C {}
+>C : C
+}
+enum E {
+>E : E
+
+    D = E["C"],
+>D : E.D
+>E["C"] : typeof E.C
+>E : typeof E
+>"C" : "C"
+}
+
+// Alias exports that resolve to enum members must still constant-evaluate (like E.C).
+enum F {
+>F : F
+
+    A = 1,
+>A : F.A
+>1 : 1
+}
+namespace E2 {
+>E2 : typeof E2
+
+    export import C = F.A;
+>C : F.A
+>F : F
+>A : F.A
+}
+enum E2 {
+>E2 : E2
+
+    D = E2["C"],
+>D : E2.D
+>E2["C"] : F
+>E2 : typeof E2
+>"C" : "C"
+
+    Next,
+>Next : E2.Next
+}
+
diff --git a/tsc/testdata/tests/cases/compiler/enumInitializerNamespaceExportElementAccess.ts b/tsc/testdata/tests/cases/compiler/enumInitializerNamespaceExportElementAccess.ts
new file mode 100644
index 0000000000000..9a40c89e1baf4
--- /dev/null
+++ b/tsc/testdata/tests/cases/compiler/enumInitializerNamespaceExportElementAccess.ts
@@ -0,0 +1,21 @@
+// Namespace export merged with enum must not be treated as an enum member via E["C"].
+// Previously panicked: Unhandled case in Node.MemberList: KindModuleBlock
+
+namespace E {
+    export class C {}
+}
+enum E {
+    D = E["C"],
+}
+
+// Alias exports that resolve to enum members must still constant-evaluate (like E.C).
+enum F {
+    A = 1,
+}
+namespace E2 {
+    export import C = F.A;
+}
+enum E2 {
+    D = E2["C"],
+    Next,
+}